It creates an osmosis effect due to which the salt draws fluids from your throat. という文の due to which というところの which は関係代名詞なので、先行詞となる名詞に置き換えて関係節を単独の文にしてみると、文の内容がわかりやすくなります。
It creates an osmosis effect. Due to <the osmosis effect,> the salt draws fluids from your throat.